|
|
1-(6-hydroxypyrid-3-yl)-4-(methylamino)-butan-1-one + H2O + oxidized_electron_transfer_flavoprotein + H+ <=> 6-hydroxy-3-succinoylsemialdehyde-pyridine + methylamine + reduced_flavodoxin
|
1.5.8.M1
|
–
|
| |
MetaCyc:
RXN-16529
|
|
|
|
6-hydroxy-3-succinoylsemialdehyde-pyridine + NADP+ + H2O <=> 4-(6-hydroxypyridin-3-yl)-4-oxobutanoate + NADPH + H+
|
1.2.1
|
–
|
| |
MetaCyc:
RXN-16530
|
|
|
|
6-hydroxy-L-nicotine + O2 <=> 6-hydroxy-N-methylmyosmine + H2O2
|
1.5.3.5
(S)-6-hydroxynicotine oxidase
|
–
|
| |
BRENDA:
BR51483
KEGG:
R11048
MetaCyc:
RXN-16526
|
|
|
|
6-hydroxy-N-methylmyosmine + H2O <=> 1-(6-hydroxypyrid-3-yl)-4-(methylamino)-butan-1-one
|
1.5.3.5
(S)-6-hydroxynicotine oxidase
1.5.3.6
(R)-6-hydroxynicotine oxidase
|
–
–
|
| |
BRENDA:
BR51484
KEGG:
R11049
MetaCyc:
RXN-16527
|
|
|
|
Maleamate + H2O <=> Maleate + NH3
|
3.5.1.107
maleamate amidohydrolase
|
–
|
| |
BRENDA:
BR49201
KEGG:
R03540
MetaCyc:
RXN-646
SABIO-RK:
3324
|
|
|
|
Nicotine + H2O + oxidized_pseudoazurin <=> 6-hydroxy-L-nicotine + reduced_pseudoazurin + H+
|
1.5.99.4
nicotine dehydrogenase
|
–
|
| |
MetaCyc:
NICOTINE-DEHYDROGENASE-RXN
|
|
|
|
2,5-dihydroxypyridine + O2 <=> H+ + N-formylmaleamic_acid
|
1.13.11.9
2,5-dihydroxypyridine 5,6-dioxygenase
|
–
|
| |
BRENDA:
BR37124
KEGG:
R09125
MetaCyc:
1.13.11.9-RXN
SABIO-RK:
15162
|
|
|
|
Maleate <=> fumarate
|
5.2.1.1
maleate isomerase
|
–
|
| |
BRENDA:
BR208
KEGG:
R01087
MetaCyc:
MALEATE-ISOMERASE-RXN
|
|
|
|
4-(6-hydroxypyridin-3-yl)-4-oxobutanoate + NADH + O2 + H+ <=> 2,5-dihydroxypyridine + succinate_semialdehyde + NAD+ + H2O
|
1.14.13.163
6-hydroxy-3-succinoylpyridine 3-monooxygenase
|
–
|
| |
BRENDA:
BR49101
KEGG:
R09472
MetaCyc:
RXN-13081
|
|
|
|
N-formylmaleamic_acid + H2O <=> H+ + Maleamate + formate
|
3.5.1.106
N-formylmaleamate deformylase
|
–
|
| |
BRENDA:
BR49200
KEGG:
R09126
MetaCyc:
RXN-11318
|
|
